Poly[[aqua­tris­(μ3-hexa­methyl­ene­tetra­mine-κ3 N,N′,N′′)tris­(p-toluene­sulfonato-κO)tris­ilver(I)] trihydrate]

نویسندگان

  • Hua Wu
  • Meng-Xiang Shang
  • Shao-Ping ShangGuan
چکیده

There are three Ag(I) cations, three p-toluene-sulfonate (pts) anions, three hexa-methyl-ene-tetra-mine (hmt) mol-ecules and four water mol-ecules in the asymmetric unit of the title coordination polymer, {[Ag(3)(C(7)H(7)O(3)S)(3)(C(6)H(12)N(4))(3)(H(2)O)]·3H(2)O}(n). Two of the pts anions show positional disorder of their O atoms in 0.60:0.40 and 0.50:0.50 ratios. The Ag(I) ion is coordinated by three hmt mol-ecules in an approximate trigonal-planar AgN(3) arrangement. In each case, longer Ag-O bonds to a water mol-ecule and a pts anion complete a distorted trigonal-bipyramidal AgN(3)O(2) geometry for the metal ion. In the crystal, the bridging hmt mol-ecules and pts ions generate a wave-like layer parallel to (001) and O-H⋯O hydrogen-bonding inter-actions consolidate the packing.

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عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010